1. Research Expertise
  2. Biography
  3. Collaborations
  4. Publications
Research Expertise -

Current Research Interests

The local structure of many materials is often the key to understanding their properties. The pair distribution function (PDF) can be used to probe the structure of solids, amorphous materials and liquids on the local scale. The PDF is quantitative histogram of inter-atomic distances, and as such can be used for local structure refinement in much the same was as Bragg diffraction data are used for average structure refinement. The technique has wide applications in fields as diverse as battery and fuel cell materials, pharmaceuticals and the earth sciences.

The main theme underlying my research is in the determination of structures using powder diffraction techniques. Structure underlies many of the properties of any system, and so is a vial starting point for any system studied. I am particularly interested in materials for the energy economy, such as hydrogen storage materials, lithium ion conductors and fuel cell materials. The aim is to investigate short-range ion ordering these systems in order to understand their true local structure and gain an insight into their ion transport properties.
Other research activities include the development of fundamental parameter descriptions of 2-D area detectors for Rietveld analysis of powder diffraction data and instrumental functions for Pair Distribution Function analysis.
XPDF (I15-1) is a new beamline which has just become operational. My role is now to help new and experience PDF users to operate the beamline to get the best possible data for their science, as well looking for new developments and improvements to the beamline and performing my own research in the field of local structure analysis.
Biography - +

Phil obtained a MSci degree in Chemistry from the University of Birmingham (U.K.) in 2004. He continued at Birmingham researching under Dr Paul Anderson first for a PhD and then as a post-doc for the United Kingdom Sustainable Hydrogen Energy Consortium (UK-SHEC) researching complex hydrides for hydrogen storage and the link between reversibility and lithium ion conductivity.

In 2011 Phil joined the University of Liverpool (U.K.) as a post-doc working for Professor Matt Rosseinsky on the local structure of functional oxides, using X-ray and neutron Pair Distribution Function (PDF) analysis to study the short-range structure of materials. Structural characterisation from powders has been a theme underlying all of Phil's research; he has investigated a broad range of systems including complex hydrides, oxide ion conductors, metal organic frameworks, superconductors and ferroelectric materials. As Beamline Scientist at Diamond, Phil will be setting up and running I15-1, the new X-ray PDF beamline, where he is dedicated to constructing a beamline for the rapid and robust production of high-quality X-ray PDF data.

Collaborations - +


Prof Andrew Goodwin, University of Oxford
The characterisation of correlated defects and disordered systems
PhD co-supervisor

Dr Paul Anderson and Prof Peter Slater, University of Birmingham
Disordered mixed-anion materials for lithium ion conduction
PhD co-supervisor

Dr Ivana Evans and Prof John Evans, Durham University
Materials for energy applications: Structure, properties and dynamics
PhD co-supervisor

Publications - +


S. A. Kondrat, P. J. Smith, P. P. Wells, P. A. Chater, J. H. Carter, D. J. Morgan, E. M. Fiordaliso, J. B. Wagner, T. E. Davies, L. Lu, J. K. Bartley, S. H. Taylor, M. S. Spencer, C. J. Kiely, G. J. Kelly, C. W. Park, M. J. Rosseinsky and G. J. Hutchings, "Stable amorphous georgeite as a precursor to a high-activity catalyst", Nature, 2016, 531, 83.
DOI: 10.1038/nature16935

J. P. Sutter, P. A. Chater, M. R. Hillman, D. S. Keeble, M. G. Tucker and H. Wilhelm, "Three-energy focusing Laue monochromator for the diamond light source x-ray pair distribution function beamline I15-1", AIP Conf. Proc., 2016, 1741, 040005.
DOI: 10.1063/1.4952877

E. F. Baxter, T. D. Bennett, A. B. Cairns, N. J. Brownbill, A. L. Goodwin, D. A. Keen, P. A. Chater, F. Blanc and A. K. Cheetham, "A comparison of the amorphization of zeolitic imidazolate frameworks (ZIFs) and aluminosilicate zeolites by ball-milling", Dalton Trans., 2016, 45, 4258.
DOI: 10.1039/C5DT03477A

A. A. Coelho, P. A. Chater and A. Kern, "Fast synthesis and refinement of the atomic pair distribution function", J. Appl. Cryst., 2015, 48, 869.
DOI: 10.1107/S1600576715007487

M. J. Cliffe, W. Wan, X. Zou, P. A. Chater, A. K. Kleppe, M. G. Tucker, H. Wilhelm, N. P. Funnell, F.-X. Coudert and A. L. Goodwin, "Correlated defect nanoregions in a metal–organic framework", Nat. Commun., 2014, 5, 4176.
DOI: 10.1038/ncomms5176

Philip Chater


Philip Chater is a Beamline Scientist on the XPDF beamline, I15-1. Phil joined Diamond in August 2013 after working at the University of Birmingham and University of Liverpool.

Email: philip.chater@diamond.ac.uk
Tel: +44 (0) 1235 778677

Key Research Area

Other Specialist Areas

  • Local structure
  • Physical Science

Latest Publications

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